Gọi x là khối lượng Fe

Khối lượng Pb là: 3,696.x

Ta có: mPb+mFe=52,6⇔x+3,696x=52,6⇒x≃11,2g

mFe≃11,2g→nFe=0,2mol

mPb=11,2.3,696≃41,4g→nPb=\(\dfrac{41,4}{207}\)=0,2mol

=>%Fe=\(\dfrac{11,2}{52.6}.100=21,29\%\)

=>%Pb=78,71%

PbO+H2→Pb+H2O

0,2 <-----0,2

Fe2O3+3H2→2Fe+3H2O

0,3 <------0,2

nH2=0,2+0,3=0,5mol→VH2=0,5.22,4=11,2l

1/ Theo ĐLBT KL, có: m_KL + m_Cl2 = m_muối

⇒ m_Cl2 = 31,425 - 6,93 = 24,495 (g)

\(\Rightarrow n_{Cl_2}=\dfrac{24,495}{71}=0,345\left(mol\right)\)

\(\Rightarrow V_{Cl_2}=0,345.22,4=7,728\left(l\right)\)

2/ Giả sử: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)

⇒ 24x + 27y = 6,93 (1)

Các quá trình:

\(Mg^0\rightarrow Mg^{+2}+2e\)

x_____________2x (mol)

\(Al^0\rightarrow Al^{+3}+3e\)

y___________3y (mol)

\(Cl_2^0+2e\rightarrow2Cl^-\)

0,345_0,69 (mol)

Theo ĐLBT mol e, có: 2x + 3y = 0,69 (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,12\left(mol\right)\\y=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,12.24=2,88\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)

Bạn tham khảo nhé!

a)\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

PTHH: 2Al + 3H₂SO₄ → Al₂(SO₄)₃ + 3H₂

Mol:       x                                                     1,5x

PTHH: Mg + H₂SO₄ → MgSO₄ + H₂

Mol:      y                                                 y

Ta có: \(\left\{{}\begin{matrix}27x+24y=5,1\\1,5x+y=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{0,1.27.100\%}{5,1}=52,94\%;\%m_{Mg}=100-52,94=47,06\%\)

b) 

PTHH: 2Al + 3H₂SO₄ → Al₂(SO₄)₃ + 3H₂

Mol:      0,1      0,15                  0,05                            

PTHH: Mg + H₂SO₄ → MgSO₄ + H₂

Mol:     0,1       0,1                 0,1

\(m_{ddH_2SO_4}=\dfrac{\left(0,1+0,15\right).98.100}{9,8}=250\left(g\right)\)

m_{dd sau pứ} = 5,1+250-0,15.2 = 254,8(g)

\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{254,8}=6,71\%\)

\(C\%_{ddMgSO_4}=\dfrac{0,1.120.100\%}{254,8}=4,71\%\)

\(a,\) Đặt \(\begin{cases} n_{Fe}=x(mol)\\ n_{Al}=y(mol) \end{cases}\Rightarrow 56x+27y=22(1)\)

\(n_{H_2}=\dfrac{17,92}{22,4}=0,8(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow x+1,5y=0,8(2)\\ (1)(2)\Rightarrow \begin{cases} x=0,2(mol)\\ y=0,4(mol) \end{cases} \Rightarrow \begin{cases} \%_{Fe}=\dfrac{0,2.56}{22}.100\%=50,91\%\\ \%_{Al}=100\%-50,91\%=49,09\% \end{cases} \)

\(b,\Sigma n_{HCl}=2n_{Fe}+3n_{Al}=0,4+1,2=1,6(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{1,6.36,5}{3,7\%}=1578,38\%\)

a) Gọi số mol Al, Mg là a, b

=> 27a + 24b = 6,3

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

            a------------------------->1,5a

            Mg + 2HCl --> MgCl₂ + H₂

            b--------------------------->b

=> \(1,5a+b=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

=> a = 0,1; b = 0,15

=> \(\left\{{}\begin{matrix}m_{Al}=0,1.27=2,7\left(g\right)\\m_{Mg}=0,15.24=3,6\left(g\right)\end{matrix}\right.\)

b) 

PTHH: M_xO_y + yH₂ --t^o--> xM + yH₂O

             \(\dfrac{0,3}{y}\)<--0,3

=> \(M_{M_xO_y}=x.M_M+16y=\dfrac{17,4}{\dfrac{0,3}{y}}\)

=> \(M_M=21.\dfrac{2y}{x}\left(g/mol\right)\)

Xét \(\dfrac{2y}{x}=1\) => Loại

Xét \(\dfrac{2y}{x}=2\) => Loại

Xét \(\dfrac{2y}{x}=3\) => Loại

Xét \(\dfrac{2y}{x}=\dfrac{8}{3}\) => M_M = 56 (g/mol) => M là Fe 

a, ptpứ:

\(Mg+2HCl\rightarrow MgCl_2+H_2\left(1\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(2\right)\)

gọi số mol Mg là x mol , số mol Al là y mol ( x; y >0)

ta có pt : \(24x+27y=6,3\left(3\right)\)

theo bài : \(nH_2=0,3mol\)

theo ptpư(1) \(nH_2=nMg=xmol\)

theo ptpư(2) \(nH_2=\dfrac{3}{2}nAl=\dfrac{3}{2}ymol\)

tiếp tục có pt : \(x+\dfrac{3}{2}y=0,3\left(4\right)\)

từ (3) và (4) ta có hệ pt:

\(24x+27y=6,3\\ x+\dfrac{3}{2}y=0,3\)

<=> \(x=0,15\) ; \(y=0,1\)

\(mMg=24x=24.0,15=3,6gam\)

\(mAl=27y=27.0,1=2,7gam\)

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

               2a______3a__________a_______3a    (mol)

            \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)

                b_______b________b______b        (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}27\cdot2a+24b=7,8\\3a+b=\dfrac{200\cdot19,6\%}{98}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,1\cdot24=2,4\left(g\right)\\m_{Al}=5,4\left(g\right)\\n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)=n_{MgSO_4}\\n_{H_2}=0,4\left(mol\right)\Rightarrow m_{H_2}=0,4\cdot2=0,8\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=207\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1\cdot342}{207}\cdot100\%\approx16,52\%\\C\%_{MgSO_4}=\dfrac{0,1\cdot120}{207}\cdot100\%\approx5,8\%\end{matrix}\right.\)

\(a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ \Rightarrow n_{Zn}=n_{H_2}=\dfrac{3,7185}{24,79}=0.,15(mol)\\ \Rightarrow m_{Zn}=0,15.65=9,75(g)\\ \Rightarrow \%_{Zn}=\dfrac{9,75}{10}.100\%=97,5\%\\ \Rightarrow \%_{Cu}=100\%-97,5\%=2,5\%\\ b,n_{HCl}=2n_{H_2}=0,3(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{0,3.36,5}{14\%}=78,21(g)\)